| |
|
| Kalborsite |
|K6 B(OH)4Cl|[Al4Si6O20] |
| |
|
|
|
| Morphology: |
|
|
| |
Equant, cubic-appearing
crystals to 2 mm. |
|
 |
|
|
| |
|
| Physical
properties: |
|
|
Kalborsite crystal from Rasvumchorr Mt,
Khibiny Massif, Murmansk Oblast, Russia (Source: mindat.org). |
| |
Cleavage: perfect on
{110}.
Hardness: 5 - 6.
Density = 2.5 gm/cm3.
Luster: vitreous.
Streak: white.
|
| |
| |
|
| Optical
properties: |
|
| |
Color: Colorless to faint
pinkish brown.
Uniaxial (+). ω = 1.525, ε = 1.525, δ = < 0.001 |
|
| |
|
| Crystallography: |
|
| |
Unit cell
data:
a 9.851, c 13.060 Å.
Z = 2, Space group P -421c. (Malinovskii and Belov
1980) |
|
| |
|
| |
|
| |
|
|
|
| Name: |
|
| |
Kalborsite was described
and named by Khomyakov et al. (1980). The type material
comes from Mount Rasvumchorr, Khibina massif, Kola Peninsula,
Russia, and the name is for the composition. |
| |
|
|
|
| Crystal structure: |
|
| |
The kalborsite framework
(Malinovskii and Belov 1980), like that of tetragonal edingtonite,
is highly ordered
despite the Si/Al ratio being slightly different from 1.5 (1.54 and
1.45 for the two analyzed samples), but has K+, Cl-,
and B(OH)4- in the channels. In the figure projected
along [001], SiO4 tetrahedra are white, AlO4 are gray, B(OH)4
are yellow, and K cations are orange and Cl anions are green.
Doubling of the c-axis relative to edingtonite occurs because of
ordering of [B(OH)4] tetrahedra and Cl-. Both
are bonded to non-framework K, along the [001] channels. [B(OH)4]
and Cl- sites correspond to the Ba sites in edingtonite.
The different size of [B(OH)4] and Cl- anions
causes different distortions of two adjacent cages.
|
| |
 |
| |
|
| Chemical composition: |
| |
By electron microprobe, the average of three
analyses corresponds to K6.04B1.35(Al3.93Si6.07)
Σ=10.00O22.58Cl0.99(OH)4. |
| Occurrences: |
| |
Kalborsite occurs in the
pegmatitic veins in two localities, Mt. Rasvumchorr and Mt.
Kukisvumchorr, in the Khibina massif of the Kola Peninsula, Russia.
At Mt. Rasvumchorr kalborsite it is disseminated in lovozerite-rich
pegmatite, containing potassium feldspar, nepheline, aegerine,
eudialyte, lomosovite, lamprophyllite, shcherbakovite, and magnesian
astrophyllite. It is mostly confined to clusters of pectolite that
form rims around lovozerite masses. Khomyakov et al.
(1980) suggest that kalborsite was originally associated with
zirsinalite, which developed from eudialyte through reactions with
late fluids supersaturated with alkalis, boron, and volatiles.
On Mt. Kukisvumchorr kalborsite occurs in an alkaline, cancrinite
pegmatitic vein as part of a hyperagpaitic assemblage of
villiaumite, pirssonite, rasvumite, thermonatrite, among others
(Pekov and Chukanov 1996). |
| |
|
| References: |
| |
Khomyakov, A.P.,
Sandomirskaya, S.M. and Malinovskii, Yu. A. (1980) Kalborsite,
K6BAl4Si6O20(OH)4Cl, a new mineral.
Dokl. Akad. Nauk SSSR 252, 131-134 (translated).
Malinovskii, Yu. A. and Belov, N.V. (1980) Crystal structure of
kalborsite. Sov. Phys. Dokl. 25, 331-334 (translated).
Pekov, I.V. and Chukanov, N.V. (1996) New data on kalborsite. Zap.
Vses. Mineral. Obshchest. 125, 55-59 (in Russian).
Updated: August 2025. |